Solution Manual for Organic Structural Spectroscopy, 2/E 2nd Edition Joseph B. Lambert, Scott Gronert, Herbert F. Shurvell, David Lightner, Robert Graham Cooks digital download immediately after payment is complete.

Product details:

• ISBN-10 ‏ : ‎ 0321592565
• ISBN-13 ‏ : ‎ 978-0321592569
• Author: Joseph B. Lambert

Ideal for any practicing or future organic chemist or biochemist, Organic Structural Spectroscopypresents the fundamentals of all four principal spectroscopic methods: nuclear magnetic resonance spectroscopy, mass spectrometry, infrared spectroscopy, and ultraviolet-visible spectroscopy. Each topic is examined in depth by an experienced author who is a practicing expert in that area. The material begins at the most elementary level and progresses to the level required for organic research. Among many other enhancements, the Second Edition offers an entirely new discussion of mass spectrometry, with comprehensive coverage of new ionization and fragmentation methods, and treatment of NMR from the basics to advanced 2D methods.

Table contents:

Chapter 1 Introduction

1-1 The Spectroscopic Approach to Structure Determination

1-2 Contributions of Different Forms of Spectroscopy

1-3 The Electromagnetic Spectrum

1-4 Molecular Weight and Molecular Formula

1-5 Structural Isomers and Stereoisomers

Problems

Part I NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY

Chapter 2 Introduction

2-1 Magnetic Properties of Nuclei

2-2 The Chemical Shift

2-3 Excitation and Relaxation

2-4 Pulsed Experiments

2-5 The Coupling Constant

2-6 Quantification and Complex Splitting

2-7 Commonly Studied Nuclides

2-8 Dynamic Effects

2-9 Spectra of Solids

2-10 Experimental Methods

Problems

Tips on Solving NMR Problems

Bibliography

Chapter 3 The Chemical Shift

3-1 Factors That Influence Proton Shifts

3-2 Proton Chemical Shifts and Structure

3-3 Medium and Isotope Effects

3-4 Factors That Influence Carbon Shirts

3-5 Carbon Chemical Shifts and Structure

3-6 Tables of Chemical Shifts

Problems

Further Tips on Solving NMR Problems

Bibliography

Chapter 4 The Coupling Constant

4-1 First-Order Spectra

4-2 Chemical and Magnetic Equivalence

4-3 Signs and Mechanisms

4-4 Couplings over One Bond

4-5 Geminal Couplings

4-6 Vicinal Couplings

4-7 Long-Range Couplings

4-8 Spectral Analysis

4-9 Second-Order Spectra

4-10 Tables of Coupling Constants

Problems

Bibliography

Chapter 5 Further Topics in One-Dimensional NMR

5-1 Spin-Lattice and Spin-Spin Relaxation

5-2 Reactions on the NMR Time Scale

5-3 Multiple Resonance

5-4 The Nuclear Overhauser Effect

5-5 Spectral Editing

5-6 Sensitivity Enhancement

5-7 Carbon Connectivity

5-8 Phase Cycling, Composite Pulses, and Shaped Pulses

Problems

Bibliography

Chapter 6 Two-Dimensional NMR

6-1 Proton-Proton Correlation Through Coupling

6-2 Proton-Heteronucleus Correlation

6-3 Proton-Proton Correlation Through Space or Chemical Exchange

6-4 Carbon-Carbon Correlation

6-5 Higher Dimensions

6-6 Pulsed Field Gradients

6-7 Summary of Two-Dimensional Methods

Problems

Bibliography

Part II MASS SPECTROMETRY

Chapter 7 Instrumentation and Theory

7-1 Introduction

7-2 Ionization Methods

7-3 Mass Analysis

7-4 Sample Preparation

Chapter 8 Ion Activation and Fragmentation

8-1 Basic Principles

8-2 Methods and Energetics

8-3 Functional Groups

Chapter 9 Structural Analysis

9-1 Molecular Weights

9-2 Molecular Formula

9-3 Structures from Fragmentation Patterns

9-4 Polymers

Chapter 10 Quantitative Applications

10-1 Quantification of Analytes

10-2 Thermochemistry

Part III VIBRATIONAL SPECTROSCOPY

Chapter 11 Introduction

11-1 Introduction

11-2 Vibrations of Molecules

11-3 Infrared and Raman Spectra

11-4 Units and Notation

11-5 Infrared Spectra: Dispersive and Fourier Transform

11-6 Sampling Methods for Infrared Transmission Spectra

11-7 Raman Spectroscopy

11-8 Raman Sampling Methods

11-9 Depolarization Measurements

11-10 Infrared Reflection Spectroscopy

Problems

Bibliography

Chapter 12 Group Frequencies

12-1 Introduction

12-2 Factors Affecting Group Frequencies

12-3 Infrared Group Frequencies

12-4 Raman Group Frequencies

12-5 Preliminary Analysis

12-6 The CH Stretching Region (3340-2700 cm-1)

12-7 The Carbonyl Stretching Region (1850-1650 cm-1)

12-8 Aromatic Compounds

12-9 Compounds Containing Methyl Groups

12-10 Compounds Containing Methylene Groups

12-11 Unsaturated Compounds

12-12 Compounds Containing Oxygen

12-13 Compounds Containing Nitrogen

12-14 Compounds Containing Phosphorus and Sulfur

12-15 Heterocyclic Compounds

12-16 Compounds Containing Halogens

12-17 Boron, Silicon, Tin, Lead, and Mercury Compounds

12-18 Isotopically Labeled Compounds

12-19 Using the Literature on Vibrational Spectroscopy

Problems

Bibliography

Part IV ELECTRONIC ABSORPTION SPECTROSCOPY

Chapter 13 Introduction and Experimental Methods

13-1 Introduction

13-2 Measurement of Ultraviolet-Visible Light Absorption

13-3 Quantitative Measurements

13-4 Electronic Transitions

13-5 Experimental Aspects

Problems

Bibliography

Chapter 14 Structural Analysis

14-1 Isolated Chromophores

14-2 Conjugated Chromophores

14-3 Aromatic Compounds

14-4 Important Naturally Occurring Chromophores

14-5 The Woodward-Fieser Rules

14-6 Steric Effects

14-7 Solvent Effects and Dynamic Equilibria

14-8 Hydrogen Bonding Studies

14-9 Homoconjugation

14-10 Charge Transfer Band

14-11 Worked Problems

Problems

Bibliography

Chapter 15 Integrated Problems

People also search:

organic chemistry 2 spectroscopy

organic structures from spectra